Which “exotic salt” can lower water's freezing point by –70 °C?When it rains, it puddles. Spilled salt...

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Which “exotic salt” can lower water's freezing point by –70 °C?


When it rains, it puddles. Spilled salt cycles between wet and dry with humidity. Is this akin to a phase change?How can melting point equal freezing point?What non-toxic non-water substances have a freezing point very close to water's?How can water exist in three states in freezing point?How to determine which aqueous solution has the largest freezing point depressionCan any solute be used to lower the freezing point of water?Does this freezing point depression problem make sense?Why is the melting point of a substance is the same as its freezing point?Freezing point of oxygen-18 waterDepression of freezing pointFreezing point depression of salt solutions













3












$begingroup$


The Medium.com article Mars Phoenix Lander, 10 Years Later shows several remarkable images and discoveries on Mars by the Mars Phoenix Lander circa 2008.



One image (shown below) shows what looks like droplets of liquid water, condensed on the surface of one of the lander's legs.



The article says (emphasis mine):




Shortly after landing, the camera on Phoenix’s robotic arm captured views of blobs of material on one of the landing struts. Over time, these blobs moved, darkened, and coalesced, behaving like droplets of liquid water. The hypothesis here was that these blobs “splashed up” on the struts when the descent thrusters melted the ice exposed upon landing mentioned above.



But if liquid water isn’t stable on the martian surface, how did Phoenix observe liquid water on Mars? The key here lies in salt. If you live anywhere that gets snow, you’re probably familiar with salt as a de-icer for roads, sidewalks, etc. Salt lowers the freezing point of water, allowing it to remain liquid at temperatures lower than that of non-salty water. For example, pure water freezes at 0 °C/32 °F, but ocean saltwater freezes around −2 °C/28.4 °F. While the de-icing salts you get at the hardware store lower the freezing point by a few degrees, more exotic salts can lower the freezing point as much as −70 °C/−89 °F! Phoenix discovered some of these exotic salts in the soil around the lander—in particular, magnesium perchlorate. (note, minor editorial changes have been made)






Question: Which "exotic salt" can lower water's freezing point by −70 °C?



Is it in fact magnesium perchlorate (which was found on Mars) or is it a different salt?





enter image description here




Blobs of possible brine (really salty water) imaged on one of Phoenix’s landing struts shortly after arriving on Mars. Credit: NASA/JPL-Caltech/University of Arizona/Max Planck Institute











share|improve this question











$endgroup$








  • 2




    $begingroup$
    You know why freezing point of water is decreased by using salt? It is because of relative lowering in vapour pressure which depends on number of particles present in solution, it doesn't matter whatever sizes are or whatever the salt is, the necessary conditions are that the substance you are mixing must be non volatile and it must be a solution. So basically the more salt you mix the lower the freezing point is but there is a limit on how much you can mix salt in water. And freezing point is decreased by a few degrees only. -70° is like a dream. the text you are reading might be wrong.
    $endgroup$
    – Saurav Singh
    1 hour ago










  • $begingroup$
    Also -70 C seems awful cold for a super cooled liquid.
    $endgroup$
    – MaxW
    1 hour ago






  • 2




    $begingroup$
    @SauravSingh, vapor pressure has nothing to do with freezing point, though it does affect the boiling point.
    $endgroup$
    – DrMoishe Pippik
    46 mins ago










  • $begingroup$
    @DrMoishePippik as an aside, vapor pressure may have a role in the appearance of the droplets nonetheless. Assuming this is indeed water, it may have been the heat of the spacecraft that drove water vapor out of the Martian soil, allowing some of it to "deliquesce" on the salt-encrusted leg of the spacecraft.
    $endgroup$
    – uhoh
    40 mins ago












  • $begingroup$
    @andselisk Thanks, but is it proper to alter block quotes from external sources without indicating that the quote is no longer accurate?
    $endgroup$
    – uhoh
    29 mins ago


















3












$begingroup$


The Medium.com article Mars Phoenix Lander, 10 Years Later shows several remarkable images and discoveries on Mars by the Mars Phoenix Lander circa 2008.



One image (shown below) shows what looks like droplets of liquid water, condensed on the surface of one of the lander's legs.



The article says (emphasis mine):




Shortly after landing, the camera on Phoenix’s robotic arm captured views of blobs of material on one of the landing struts. Over time, these blobs moved, darkened, and coalesced, behaving like droplets of liquid water. The hypothesis here was that these blobs “splashed up” on the struts when the descent thrusters melted the ice exposed upon landing mentioned above.



But if liquid water isn’t stable on the martian surface, how did Phoenix observe liquid water on Mars? The key here lies in salt. If you live anywhere that gets snow, you’re probably familiar with salt as a de-icer for roads, sidewalks, etc. Salt lowers the freezing point of water, allowing it to remain liquid at temperatures lower than that of non-salty water. For example, pure water freezes at 0 °C/32 °F, but ocean saltwater freezes around −2 °C/28.4 °F. While the de-icing salts you get at the hardware store lower the freezing point by a few degrees, more exotic salts can lower the freezing point as much as −70 °C/−89 °F! Phoenix discovered some of these exotic salts in the soil around the lander—in particular, magnesium perchlorate. (note, minor editorial changes have been made)






Question: Which "exotic salt" can lower water's freezing point by −70 °C?



Is it in fact magnesium perchlorate (which was found on Mars) or is it a different salt?





enter image description here




Blobs of possible brine (really salty water) imaged on one of Phoenix’s landing struts shortly after arriving on Mars. Credit: NASA/JPL-Caltech/University of Arizona/Max Planck Institute











share|improve this question











$endgroup$








  • 2




    $begingroup$
    You know why freezing point of water is decreased by using salt? It is because of relative lowering in vapour pressure which depends on number of particles present in solution, it doesn't matter whatever sizes are or whatever the salt is, the necessary conditions are that the substance you are mixing must be non volatile and it must be a solution. So basically the more salt you mix the lower the freezing point is but there is a limit on how much you can mix salt in water. And freezing point is decreased by a few degrees only. -70° is like a dream. the text you are reading might be wrong.
    $endgroup$
    – Saurav Singh
    1 hour ago










  • $begingroup$
    Also -70 C seems awful cold for a super cooled liquid.
    $endgroup$
    – MaxW
    1 hour ago






  • 2




    $begingroup$
    @SauravSingh, vapor pressure has nothing to do with freezing point, though it does affect the boiling point.
    $endgroup$
    – DrMoishe Pippik
    46 mins ago










  • $begingroup$
    @DrMoishePippik as an aside, vapor pressure may have a role in the appearance of the droplets nonetheless. Assuming this is indeed water, it may have been the heat of the spacecraft that drove water vapor out of the Martian soil, allowing some of it to "deliquesce" on the salt-encrusted leg of the spacecraft.
    $endgroup$
    – uhoh
    40 mins ago












  • $begingroup$
    @andselisk Thanks, but is it proper to alter block quotes from external sources without indicating that the quote is no longer accurate?
    $endgroup$
    – uhoh
    29 mins ago
















3












3








3


0



$begingroup$


The Medium.com article Mars Phoenix Lander, 10 Years Later shows several remarkable images and discoveries on Mars by the Mars Phoenix Lander circa 2008.



One image (shown below) shows what looks like droplets of liquid water, condensed on the surface of one of the lander's legs.



The article says (emphasis mine):




Shortly after landing, the camera on Phoenix’s robotic arm captured views of blobs of material on one of the landing struts. Over time, these blobs moved, darkened, and coalesced, behaving like droplets of liquid water. The hypothesis here was that these blobs “splashed up” on the struts when the descent thrusters melted the ice exposed upon landing mentioned above.



But if liquid water isn’t stable on the martian surface, how did Phoenix observe liquid water on Mars? The key here lies in salt. If you live anywhere that gets snow, you’re probably familiar with salt as a de-icer for roads, sidewalks, etc. Salt lowers the freezing point of water, allowing it to remain liquid at temperatures lower than that of non-salty water. For example, pure water freezes at 0 °C/32 °F, but ocean saltwater freezes around −2 °C/28.4 °F. While the de-icing salts you get at the hardware store lower the freezing point by a few degrees, more exotic salts can lower the freezing point as much as −70 °C/−89 °F! Phoenix discovered some of these exotic salts in the soil around the lander—in particular, magnesium perchlorate. (note, minor editorial changes have been made)






Question: Which "exotic salt" can lower water's freezing point by −70 °C?



Is it in fact magnesium perchlorate (which was found on Mars) or is it a different salt?





enter image description here




Blobs of possible brine (really salty water) imaged on one of Phoenix’s landing struts shortly after arriving on Mars. Credit: NASA/JPL-Caltech/University of Arizona/Max Planck Institute











share|improve this question











$endgroup$




The Medium.com article Mars Phoenix Lander, 10 Years Later shows several remarkable images and discoveries on Mars by the Mars Phoenix Lander circa 2008.



One image (shown below) shows what looks like droplets of liquid water, condensed on the surface of one of the lander's legs.



The article says (emphasis mine):




Shortly after landing, the camera on Phoenix’s robotic arm captured views of blobs of material on one of the landing struts. Over time, these blobs moved, darkened, and coalesced, behaving like droplets of liquid water. The hypothesis here was that these blobs “splashed up” on the struts when the descent thrusters melted the ice exposed upon landing mentioned above.



But if liquid water isn’t stable on the martian surface, how did Phoenix observe liquid water on Mars? The key here lies in salt. If you live anywhere that gets snow, you’re probably familiar with salt as a de-icer for roads, sidewalks, etc. Salt lowers the freezing point of water, allowing it to remain liquid at temperatures lower than that of non-salty water. For example, pure water freezes at 0 °C/32 °F, but ocean saltwater freezes around −2 °C/28.4 °F. While the de-icing salts you get at the hardware store lower the freezing point by a few degrees, more exotic salts can lower the freezing point as much as −70 °C/−89 °F! Phoenix discovered some of these exotic salts in the soil around the lander—in particular, magnesium perchlorate. (note, minor editorial changes have been made)






Question: Which "exotic salt" can lower water's freezing point by −70 °C?



Is it in fact magnesium perchlorate (which was found on Mars) or is it a different salt?





enter image description here




Blobs of possible brine (really salty water) imaged on one of Phoenix’s landing struts shortly after arriving on Mars. Credit: NASA/JPL-Caltech/University of Arizona/Max Planck Institute








inorganic-chemistry aqueous-solution phase






share|improve this question















share|improve this question













share|improve this question




share|improve this question








edited 12 mins ago









andselisk

20.4k669133




20.4k669133










asked 2 hours ago









uhohuhoh

2,1211246




2,1211246








  • 2




    $begingroup$
    You know why freezing point of water is decreased by using salt? It is because of relative lowering in vapour pressure which depends on number of particles present in solution, it doesn't matter whatever sizes are or whatever the salt is, the necessary conditions are that the substance you are mixing must be non volatile and it must be a solution. So basically the more salt you mix the lower the freezing point is but there is a limit on how much you can mix salt in water. And freezing point is decreased by a few degrees only. -70° is like a dream. the text you are reading might be wrong.
    $endgroup$
    – Saurav Singh
    1 hour ago










  • $begingroup$
    Also -70 C seems awful cold for a super cooled liquid.
    $endgroup$
    – MaxW
    1 hour ago






  • 2




    $begingroup$
    @SauravSingh, vapor pressure has nothing to do with freezing point, though it does affect the boiling point.
    $endgroup$
    – DrMoishe Pippik
    46 mins ago










  • $begingroup$
    @DrMoishePippik as an aside, vapor pressure may have a role in the appearance of the droplets nonetheless. Assuming this is indeed water, it may have been the heat of the spacecraft that drove water vapor out of the Martian soil, allowing some of it to "deliquesce" on the salt-encrusted leg of the spacecraft.
    $endgroup$
    – uhoh
    40 mins ago












  • $begingroup$
    @andselisk Thanks, but is it proper to alter block quotes from external sources without indicating that the quote is no longer accurate?
    $endgroup$
    – uhoh
    29 mins ago
















  • 2




    $begingroup$
    You know why freezing point of water is decreased by using salt? It is because of relative lowering in vapour pressure which depends on number of particles present in solution, it doesn't matter whatever sizes are or whatever the salt is, the necessary conditions are that the substance you are mixing must be non volatile and it must be a solution. So basically the more salt you mix the lower the freezing point is but there is a limit on how much you can mix salt in water. And freezing point is decreased by a few degrees only. -70° is like a dream. the text you are reading might be wrong.
    $endgroup$
    – Saurav Singh
    1 hour ago










  • $begingroup$
    Also -70 C seems awful cold for a super cooled liquid.
    $endgroup$
    – MaxW
    1 hour ago






  • 2




    $begingroup$
    @SauravSingh, vapor pressure has nothing to do with freezing point, though it does affect the boiling point.
    $endgroup$
    – DrMoishe Pippik
    46 mins ago










  • $begingroup$
    @DrMoishePippik as an aside, vapor pressure may have a role in the appearance of the droplets nonetheless. Assuming this is indeed water, it may have been the heat of the spacecraft that drove water vapor out of the Martian soil, allowing some of it to "deliquesce" on the salt-encrusted leg of the spacecraft.
    $endgroup$
    – uhoh
    40 mins ago












  • $begingroup$
    @andselisk Thanks, but is it proper to alter block quotes from external sources without indicating that the quote is no longer accurate?
    $endgroup$
    – uhoh
    29 mins ago










2




2




$begingroup$
You know why freezing point of water is decreased by using salt? It is because of relative lowering in vapour pressure which depends on number of particles present in solution, it doesn't matter whatever sizes are or whatever the salt is, the necessary conditions are that the substance you are mixing must be non volatile and it must be a solution. So basically the more salt you mix the lower the freezing point is but there is a limit on how much you can mix salt in water. And freezing point is decreased by a few degrees only. -70° is like a dream. the text you are reading might be wrong.
$endgroup$
– Saurav Singh
1 hour ago




$begingroup$
You know why freezing point of water is decreased by using salt? It is because of relative lowering in vapour pressure which depends on number of particles present in solution, it doesn't matter whatever sizes are or whatever the salt is, the necessary conditions are that the substance you are mixing must be non volatile and it must be a solution. So basically the more salt you mix the lower the freezing point is but there is a limit on how much you can mix salt in water. And freezing point is decreased by a few degrees only. -70° is like a dream. the text you are reading might be wrong.
$endgroup$
– Saurav Singh
1 hour ago












$begingroup$
Also -70 C seems awful cold for a super cooled liquid.
$endgroup$
– MaxW
1 hour ago




$begingroup$
Also -70 C seems awful cold for a super cooled liquid.
$endgroup$
– MaxW
1 hour ago




2




2




$begingroup$
@SauravSingh, vapor pressure has nothing to do with freezing point, though it does affect the boiling point.
$endgroup$
– DrMoishe Pippik
46 mins ago




$begingroup$
@SauravSingh, vapor pressure has nothing to do with freezing point, though it does affect the boiling point.
$endgroup$
– DrMoishe Pippik
46 mins ago












$begingroup$
@DrMoishePippik as an aside, vapor pressure may have a role in the appearance of the droplets nonetheless. Assuming this is indeed water, it may have been the heat of the spacecraft that drove water vapor out of the Martian soil, allowing some of it to "deliquesce" on the salt-encrusted leg of the spacecraft.
$endgroup$
– uhoh
40 mins ago






$begingroup$
@DrMoishePippik as an aside, vapor pressure may have a role in the appearance of the droplets nonetheless. Assuming this is indeed water, it may have been the heat of the spacecraft that drove water vapor out of the Martian soil, allowing some of it to "deliquesce" on the salt-encrusted leg of the spacecraft.
$endgroup$
– uhoh
40 mins ago














$begingroup$
@andselisk Thanks, but is it proper to alter block quotes from external sources without indicating that the quote is no longer accurate?
$endgroup$
– uhoh
29 mins ago






$begingroup$
@andselisk Thanks, but is it proper to alter block quotes from external sources without indicating that the quote is no longer accurate?
$endgroup$
– uhoh
29 mins ago












1 Answer
1






active

oldest

votes


















3












$begingroup$

I recently got a chance to attend a talk by someone who was working on analytical instrumentation for ion analysis on Mars. The interesting story is that the initial results by ion-selective electrode was that Mars soil is full of nitrates. Nobody knew on Earth that the nitrate ion selective electrode is far more responsive to perchlorate than nitrate. After learning this, it was an eye opener for analytical chemists! Now they wish to use chromatography rather than electrochemistry. So this was a good lesson for us on Earth.



Now that they know it is a perchlorate ion, people did some studies on supercooled brines. See this paper: The formation of supercooled brines, viscous liquids, and low-temperature perchlorate glasses in aqueous solutions relevant to Mars J.D. Toner, D.C. Catling, and B. Light, Icarus, 233, 1 May 2014, pp 36-47 (also available here). They clearly show that if calcium or magnesium perchlorates are slowly cooled, one can get supercooled brines up to -120 Celcius. This is a rather amazing finding. They call it a glassy state.






share|improve this answer











$endgroup$













  • $begingroup$
    "Nobody knew on Earth" (!!) Let's add this to the list of "Reasons to go to Mars" ;-)
    $endgroup$
    – uhoh
    38 mins ago








  • 1




    $begingroup$
    Yes it was a surprising finding because everyone used nitrate selective electrodes without ever realizing that it also responds to perchlorate far more effectively.
    $endgroup$
    – M. Farooq
    36 mins ago












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1 Answer
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active

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active

oldest

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3












$begingroup$

I recently got a chance to attend a talk by someone who was working on analytical instrumentation for ion analysis on Mars. The interesting story is that the initial results by ion-selective electrode was that Mars soil is full of nitrates. Nobody knew on Earth that the nitrate ion selective electrode is far more responsive to perchlorate than nitrate. After learning this, it was an eye opener for analytical chemists! Now they wish to use chromatography rather than electrochemistry. So this was a good lesson for us on Earth.



Now that they know it is a perchlorate ion, people did some studies on supercooled brines. See this paper: The formation of supercooled brines, viscous liquids, and low-temperature perchlorate glasses in aqueous solutions relevant to Mars J.D. Toner, D.C. Catling, and B. Light, Icarus, 233, 1 May 2014, pp 36-47 (also available here). They clearly show that if calcium or magnesium perchlorates are slowly cooled, one can get supercooled brines up to -120 Celcius. This is a rather amazing finding. They call it a glassy state.






share|improve this answer











$endgroup$













  • $begingroup$
    "Nobody knew on Earth" (!!) Let's add this to the list of "Reasons to go to Mars" ;-)
    $endgroup$
    – uhoh
    38 mins ago








  • 1




    $begingroup$
    Yes it was a surprising finding because everyone used nitrate selective electrodes without ever realizing that it also responds to perchlorate far more effectively.
    $endgroup$
    – M. Farooq
    36 mins ago
















3












$begingroup$

I recently got a chance to attend a talk by someone who was working on analytical instrumentation for ion analysis on Mars. The interesting story is that the initial results by ion-selective electrode was that Mars soil is full of nitrates. Nobody knew on Earth that the nitrate ion selective electrode is far more responsive to perchlorate than nitrate. After learning this, it was an eye opener for analytical chemists! Now they wish to use chromatography rather than electrochemistry. So this was a good lesson for us on Earth.



Now that they know it is a perchlorate ion, people did some studies on supercooled brines. See this paper: The formation of supercooled brines, viscous liquids, and low-temperature perchlorate glasses in aqueous solutions relevant to Mars J.D. Toner, D.C. Catling, and B. Light, Icarus, 233, 1 May 2014, pp 36-47 (also available here). They clearly show that if calcium or magnesium perchlorates are slowly cooled, one can get supercooled brines up to -120 Celcius. This is a rather amazing finding. They call it a glassy state.






share|improve this answer











$endgroup$













  • $begingroup$
    "Nobody knew on Earth" (!!) Let's add this to the list of "Reasons to go to Mars" ;-)
    $endgroup$
    – uhoh
    38 mins ago








  • 1




    $begingroup$
    Yes it was a surprising finding because everyone used nitrate selective electrodes without ever realizing that it also responds to perchlorate far more effectively.
    $endgroup$
    – M. Farooq
    36 mins ago














3












3








3





$begingroup$

I recently got a chance to attend a talk by someone who was working on analytical instrumentation for ion analysis on Mars. The interesting story is that the initial results by ion-selective electrode was that Mars soil is full of nitrates. Nobody knew on Earth that the nitrate ion selective electrode is far more responsive to perchlorate than nitrate. After learning this, it was an eye opener for analytical chemists! Now they wish to use chromatography rather than electrochemistry. So this was a good lesson for us on Earth.



Now that they know it is a perchlorate ion, people did some studies on supercooled brines. See this paper: The formation of supercooled brines, viscous liquids, and low-temperature perchlorate glasses in aqueous solutions relevant to Mars J.D. Toner, D.C. Catling, and B. Light, Icarus, 233, 1 May 2014, pp 36-47 (also available here). They clearly show that if calcium or magnesium perchlorates are slowly cooled, one can get supercooled brines up to -120 Celcius. This is a rather amazing finding. They call it a glassy state.






share|improve this answer











$endgroup$



I recently got a chance to attend a talk by someone who was working on analytical instrumentation for ion analysis on Mars. The interesting story is that the initial results by ion-selective electrode was that Mars soil is full of nitrates. Nobody knew on Earth that the nitrate ion selective electrode is far more responsive to perchlorate than nitrate. After learning this, it was an eye opener for analytical chemists! Now they wish to use chromatography rather than electrochemistry. So this was a good lesson for us on Earth.



Now that they know it is a perchlorate ion, people did some studies on supercooled brines. See this paper: The formation of supercooled brines, viscous liquids, and low-temperature perchlorate glasses in aqueous solutions relevant to Mars J.D. Toner, D.C. Catling, and B. Light, Icarus, 233, 1 May 2014, pp 36-47 (also available here). They clearly show that if calcium or magnesium perchlorates are slowly cooled, one can get supercooled brines up to -120 Celcius. This is a rather amazing finding. They call it a glassy state.







share|improve this answer














share|improve this answer



share|improve this answer








edited 35 mins ago









uhoh

2,1211246




2,1211246










answered 39 mins ago









M. FarooqM. Farooq

2,370113




2,370113












  • $begingroup$
    "Nobody knew on Earth" (!!) Let's add this to the list of "Reasons to go to Mars" ;-)
    $endgroup$
    – uhoh
    38 mins ago








  • 1




    $begingroup$
    Yes it was a surprising finding because everyone used nitrate selective electrodes without ever realizing that it also responds to perchlorate far more effectively.
    $endgroup$
    – M. Farooq
    36 mins ago


















  • $begingroup$
    "Nobody knew on Earth" (!!) Let's add this to the list of "Reasons to go to Mars" ;-)
    $endgroup$
    – uhoh
    38 mins ago








  • 1




    $begingroup$
    Yes it was a surprising finding because everyone used nitrate selective electrodes without ever realizing that it also responds to perchlorate far more effectively.
    $endgroup$
    – M. Farooq
    36 mins ago
















$begingroup$
"Nobody knew on Earth" (!!) Let's add this to the list of "Reasons to go to Mars" ;-)
$endgroup$
– uhoh
38 mins ago






$begingroup$
"Nobody knew on Earth" (!!) Let's add this to the list of "Reasons to go to Mars" ;-)
$endgroup$
– uhoh
38 mins ago






1




1




$begingroup$
Yes it was a surprising finding because everyone used nitrate selective electrodes without ever realizing that it also responds to perchlorate far more effectively.
$endgroup$
– M. Farooq
36 mins ago




$begingroup$
Yes it was a surprising finding because everyone used nitrate selective electrodes without ever realizing that it also responds to perchlorate far more effectively.
$endgroup$
– M. Farooq
36 mins ago


















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